The title reaction was observed along with cyclization in the SnCl4-promoted reaction of 2-[3,4,6-tri-O-benzyl-2-deoxy-2- (p-tolylsulfanyl)-β-D-glucopyranosyl]ethanal with pent-4-en-2-ol and this result was interpreted in terms of anchimeric assistance by sulfur to the unusual fragmentation of an intermediate alkoxycarbenium ion.
V. V. Samoshin, I. P. Smoliakova, M. Han and P. H. Gross, Mendeleev Commun., 1999, 9, 219 DOI: 10.1070/MC1999v009n06ABEH001180
To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.
If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.
If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.
Read more about how to correctly acknowledge RSC content.
Please wait while we load your content...