Issue 14, 1999

Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin–rhenium carbonyl complex

Abstract

A systematic synthesis designed to connect a metalloporphyrin to a metal carbonyl moiety is demonstrated through a zinc tetraphenyl porphyrin substituted with Re(CO)3(4′-methyl-2,2′-bipyridyl)Br via an amide bond; the emission and excited state absorption spectra are dominated by porphyrin transitions.

Supplementary files

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 2269-2272

Systematic synthesis and photochemistry of tetraaryl porphyrins mono-substituted with a transition metal carbonyl: characterisation of a zinc porphyrin–rhenium carbonyl complex

C. J. Aspley, J. R. Lindsay Smith and R. N. Perutz, J. Chem. Soc., Dalton Trans., 1999, 2269 DOI: 10.1039/A903779I

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