Issue 14, 1999
From the journal:

Journal of the Chemical Society, Dalton Transactions

The first symmetrical tetrarheniumcyclodiyne type cluster containing phosphine ligands: Re4(µ-O)4Cl4[P(C6H4OMe-p)3]4

Sophia S. Lau,   Phillip E. Fanwick  and  Richard A. Walton  

Abstract

The reactions of methanol solutions of cis-Re2(µ-O2CCH3)2Cl4(H2O)2 with PAr3 (Ar = Ph, C6H4Me-p, C6H4Me-m or C6H4Cl-p) afford the quadruply bonded dirhenium(IV,II) complexes Cl2(MeO)2ReReCl2(PAr3)2, whereas P(C6H4OMe-p)3 gives the complex Re4(µ-O)4Cl4[P(C6H4OMe-p)3]4, which X-ray crystallography has shown is the first symmetrical, neutral, tetrarheniumcyclodiyne type cluster containing phosphine ligands.

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DOI
https://doi.org/10.1039/A903367J
Article type
Paper

J. Chem. Soc., Dalton Trans., 1999, 2273-2274

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The first symmetrical tetrarheniumcyclodiyne type cluster containing phosphine ligands: Re4(µ-O)4Cl4[P(C6H4OMe-p)3]4

S. S. Lau, P. E. Fanwick and R. A. Walton, J. Chem. Soc., Dalton Trans., 1999, 2273 DOI: 10.1039/A903367J

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