Issue 23, 1999

Geometric requirements in the ferriin oxidation of benzylic 1,2-diols

Abstract

The rates of ferriin [i.e. tris(1,10-phenanthroline)iron(III)] oxidation of cis- and trans-1,2-diphenylcyclohexane-1,2-diol have been found to be dramatically different; cis-1,2-diphenylcyclohexane-1,2-diol reacts a minimum of 104 times faster than the corresponding trans-isomer; implications for the oxidation of benzylic diols by ferriin are discussed.

Article information

Article type
Paper

Chem. Commun., 1999, 2359-2360

Geometric requirements in the ferriin oxidation of benzylic 1,2-diols

J. H. Penn, R. C. Plants and A. Liu, Chem. Commun., 1999, 2359 DOI: 10.1039/A905728E

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements