Issue 20, 1999

Synthesis, structural characterisation and luminescence studies of the first alkynyl stabilised platinum–cadmium complexes

Abstract

The simple 1∶2 adduct (NBu4)2[{Pt(µ-κCα2- C[triple bond, length half m-dash]CPh)4}(CdCl2)2] 2 containing unusual η2-alkyne Cd interactions, as well as the unexpected tetranuclear dimer (NBu4)2[{Pt(µ-κCαCα-C[triple bond, length half m-dash]CPh)4}2(CdCl)2] 1 stabilised by alkynyl bridging ligands and platinum–cadmium bonding interactions, have been characterised by X-ray crystallography and their luminescence properties have been also investigated.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 2045-2046

Synthesis, structural characterisation and luminescence studies of the first alkynyl stabilised platinum–cadmium complexes

J. P. H. Charmant, J. Gómez, A. G. Orpen, L. R. Falvello, J. Forniés, A. Rueda, J. Gómez, E. Lalinde and M. T. Moreno, Chem. Commun., 1999, 2045 DOI: 10.1039/A906394C

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