Issue 20, 1999

Reactive intermediates from carbonylation of ruthenium(I) carbonyl carboxylates. Isolation, molecular structures and chemical properties of dinuclear unbridged ruthenium carbonyl trifluoroacetates

Abstract

Carboxylato-bridged Ru(I) carbonyl complexes are activated by CO towards both disproportionation and reaction with dihydrogen, through the intermediacy of the unbridged metal–metal bonded valence isomers (OC)5RuRu(CO)3- (OCOCR3)2 and [Ru(CO)4(OCOCR3)]2.

Supplementary files

Article information

Article type
Paper

Chem. Commun., 1999, 2043-2044

Reactive intermediates from carbonylation of ruthenium(I) carbonyl carboxylates. Isolation, molecular structures and chemical properties of dinuclear unbridged ruthenium carbonyl trifluoroacetates

T. Funaioli, G. Fachinetti and F. Marchetti, Chem. Commun., 1999, 2043 DOI: 10.1039/A905798F

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