First structurally authenticated inorganic polymers of CuBr and CuI containing chiral bidentate N-donor ligands. Use of the Schiff base 2,2′-bis[(4S)-4-benzyl-2-oxazoline] as ligand

David M. Haddleton; David J. Duncalf; Andrew J. Clark; Martin C. Crossman; Dax Kukulj

doi:10.1039/A801104D

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First structurally authenticated inorganic polymers of CuBr and CuI containing chiral bidentate N-donor ligands. Use of the Schiff base 2,2′-bis[(4S)-4-benzyl-2-oxazoline] as ligand

David M. Haddleton, David J. Duncalf, Andrew J. Clark, Martin C. Crossman and Dax Kukulj

Abstract

The products from the reaction of CuBr and CuI with equimolar quantities of 2,2′-bis[(4S)-4-benzyl-2-oxazoline] have been characterised by X-ray crystallography and shown to comprise two different polymeric arrangements of (CuBr)_n or (CuI)_n ‘sheathed’ by bridging bidentate oxazoline ligands.

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DOI: https://doi.org/10.1039/A801104D
Article type: Paper

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New J. Chem., 1998,22, 315-318

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First structurally authenticated inorganic polymers of CuBr and CuI containing chiral bidentate N-donor ligands. Use of the Schiff base 2,2′-bis[(4S)-4-benzyl-2-oxazoline] as ligand

D. M. Haddleton, D. J. Duncalf, A. J. Clark, M. C. Crossman and D. Kukulj, New J. Chem., 1998, 22, 315 DOI: 10.1039/A801104D

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New Journal of Chemistry

First structurally authenticated inorganic polymers of CuBr and CuI containing chiral bidentate N-donor ligands. Use of the Schiff base 2,2′-bis[(4S)-4-benzyl-2-oxazoline] as ligand

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First structurally authenticated inorganic polymers of CuBr and CuI containing chiral bidentate N-donor ligands. Use of the Schiff base 2,2′-bis[(4S)-4-benzyl-2-oxazoline] as ligand

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