Issue 4, 1998
From the journal:

New Journal of Chemistry

Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]

Darren J. Cook,   Karsten J. Harlow,   Anthony F. Hill,   Tom Welton,   Andrew J. P. White  and  David J. Williams  

Abstract

The reaction of [Ru(â–·CC6H4OMe-4)Cl(CO)(PPh3)2] with [NH4][S2CNC4H8] provides the structurally characterised metallacycle [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}(S2CNC4H8)(CO)(PPh3)], related examples of which arise from the reactions of xanthate or dithiocarbamate salts with the alkylidene compounds [MCl2([double bond, length as m-dash]CHR)- (CO)(PPh3)2] (M=Ru or Os; R=Ph or C6H4OMe-4) and [OsCl([double bond, length as m-dash]CHR)(OH2)(CO)(PPh3)2]ClO4.

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Article information

DOI
https://doi.org/10.1039/A801542B
Article type
Paper

New J. Chem., 1998,22, 311-314

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Alkylidene–Dithiocarbamate coupling—crystal structure of [Ru{κ2-CH(C6H4OMe-4)SC(NC4H8)S}{κ2-S2CNC4H8}(CO)(PPh3)]

D. J. Cook, K. J. Harlow, A. F. Hill, T. Welton, A. J. P. White and D. J. Williams, New J. Chem., 1998, 22, 311 DOI: 10.1039/A801542B

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