Issue 1, 1998

Electrochemical transformation of malonate and alkylidenemalonates into 3-substituted cyclopropane-1,1,2,2-tetracarboxylates

Abstract

Electrolysis of malonate and alkylidenemalonates in an undivided cell in methanol in the presence of sodium bromide or sodium iodide as mediators leads to substituted 1,1,2,2-cyclopropanetetracarboxylates in 80-95% substance and 60-75% current yield.

Article information

Article type
Paper

Mendeleev Commun., 1998,8, 15-17

Electrochemical transformation of malonate and alkylidenemalonates into 3-substituted cyclopropane-1,1,2,2-tetracarboxylates

M. N. Elinson, S. K. Feducovich, S. G. Bushuev, A. A. Zakharenkov, D. V. Pashchenko and G. I. Nikishin, Mendeleev Commun., 1998, 8, 15 DOI: 10.1070/MC1998v008n01ABEH000893

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