Issue 8, 1998
From the journal:

Journal of the Chemical Society, Dalton Transactions

Yttrium β-diketonate complexes with triglyme: ionic and neutral isomers and outer-sphere co-ordination of triglyme †

Kimberly D. Pollard,   Jagadese J. Vittal,   Glenn P. A. Yap  and  Richard J. Puddephatt  

Abstract

While monoglyme and diglyme reacted with [YIII(hfac)3] to give eight- and nine-co-ordinate neutral complexes [Y(hfac)3(glyme)], 1 and 2 respectively, reactions with triglyme or tetraglyme resulted in disproportionation giving the ionic complexes [Y(hfac)2(glyme)]+[Y(hfac)4]–, 3a and 4 respectively; sublimation of 3a with adventitious water gave the outer-sphere glyme complex [Y(hfac)3(OH2)2]·MeO(CH2CH2O)3Me which has an infinite chain helical structure.

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Article information

DOI
https://doi.org/10.1039/A801344F
Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 1265-1268

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Yttrium β-diketonate complexes with triglyme: ionic and neutral isomers and outer-sphere co-ordination of triglyme †

K. D. Pollard, J. J. Vittal, G. P. A. Yap and R. J. Puddephatt, J. Chem. Soc., Dalton Trans., 1998, 1265 DOI: 10.1039/A801344F

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