Results from structural studies have demonstrated that the ferrocenyl substituent lengthens C–O bonds at the α position provided that the C–O bond is antiperiplanar with respect to the C–Fe bond, these structural effects parallel the known solution behaviour of α-ferrocenyl esters.
B. R. Pool, C. Sun and J. M. White, J. Chem. Soc., Dalton Trans., 1998, 1269 DOI: 10.1039/A801652F
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