Issue 5, 1998

Anion-induced migration reaction of acetylide from iron to cyclopentadienyl in (cyclopentadienyl)irondicarbonyl(acetylide) complexes

Abstract

The anion-induced migration reaction of acetylide in (η5-C5H5)Fe(CO)2(C[triple bond, length half m-dash]CPh) 1 was observed in a sequential treatment of lithium diisopropylamide then MeI or MeC(O)Cl resulting in (η5-C5H4C[triple bond, length half m-dash]CPh)Fe(CO)2Me 2 or (η5-C5H4C[triple bond, length half m-dash]CPh)Fe(CO)2C(O)Me 3, respectively, the structure of 3 being confirmed by a single-crystal X-ray study.

Article information

Article type
Paper

J. Chem. Soc., Dalton Trans., 1998, 741-744

Anion-induced migration reaction of acetylide from iron to cyclopentadienyl in (cyclopentadienyl)irondicarbonyl(acetylide) complexes

L. Liu, K. Chang and Y. Wen, J. Chem. Soc., Dalton Trans., 1998, 741 DOI: 10.1039/A709100A

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Spotlight

Advertisements