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Issue 5, 1998
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Synthesis and molecular structure of Bi4Ba44-O)23-OEt)8(µ-OEt)42-thd)4 (Hthd = 2,2,6,6-tetramethylheptane-3,5-dione). An example of the formulation of a mixed-metal alkoxide assisted by dioxygen

Abstract

The reaction between bismuth ethoxide and [Ba(thd)2]4 (Hthd = 2,2,6,6-tetramethylheptane-3,5-dione) afforded the octanuclear Bi4Ba44-O)23-OEt)8(µ-OEt)42-thd)4 species in high yield, the structure being determined by single-crystal X-ray diffraction; the formation of this species was precluded in anaerobic media.

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Article type: Paper
DOI: 10.1039/A708052B
J. Chem. Soc., Dalton Trans., 1998, 737-740

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    Synthesis and molecular structure of Bi4Ba44-O)23-OEt)8(µ-OEt)42-thd)4 (Hthd = 2,2,6,6-tetramethylheptane-3,5-dione). An example of the formulation of a mixed-metal alkoxide assisted by dioxygen

    S. Parola, R. Papiernik, L. G. Hubert-Pfalzgraf and C. Bois, J. Chem. Soc., Dalton Trans., 1998, 737
    DOI: 10.1039/A708052B

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