The rigid bis-porphyrinic host 2 forms 1:1 complexes with rigid 5,15-bis(4-pyridyl)porphyrins and both 1:1 and 2:1 complexes with tetrapyridylporphyrin 4, with the latter complex providing a new example of a self-assembled system containing an enclosed molecular environment.
M. R. Johnston, R. N. Warrener and M. J. Gunter, Chem. Commun., 1998, 2739 DOI: 10.1039/A807339B
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