The nature of the interaction of molecular fluorine and Lewis bases B from a comparison of the properties of B···F2 and B···HF
Abstract
Comparison of angular geometries, radial geometries and intermolecular stretching force constants kς of the two series of complexes B···F2 and B···HF, where B is H2S, HCN, CH3CN, H2O, (CH2)2O or NH3, allows conclusions about the nature of the interaction in B···F2 and the shape of the F atom in F2.