Issue 24, 1998

The nature of the interaction of molecular fluorine and Lewis bases B from a comparison of the properties of B···F2 and B···HF

Abstract

Comparison of angular geometries, radial geometries and intermolecular stretching force constants kς of the two series of complexes B···F2 and B···HF, where B is H2S, HCN, CH3CN, H2O, (CH2)2O or NH3, allows conclusions about the nature of the interaction in B···F2 and the shape of the F atom in F2.

Article information

Article type
Paper

Chem. Commun., 1998, 2737-2738

The nature of the interaction of molecular fluorine and Lewis bases B from a comparison of the properties of B···F2 and B···HF

A. C. Legon, Chem. Commun., 1998, 2737 DOI: 10.1039/A807791F

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