Modulation of iron reduction potential by deprotonation at a remote site
Abstract
Remote site deprotonation of a coordinated imidazole ligand switches the reduction potential of coordinated iron over a narrow pH range from +0.920 to –0.460 V.
Remote site deprotonation of a coordinated imidazole ligand switches the reduction potential of coordinated iron over a narrow pH range from +0.920 to –0.460 V.
R. F. Carina, L. Verzegnassi, A. F. Williams and G. Bernardinelli, Chem. Commun., 1998, 2681 DOI: 10.1039/A807321J
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