Caesium/nanoporous carbon materials have a very high affinity for hydrogen, breaking the extremely energetic C–H bond in benzene and promoting its condensation to biphenyl, opening a new class of chemical reactions to heterogeneous catalysis.
M. G. Stevens, K. M. Sellers, H. C. Foley and S. Subramoney, Chem. Commun., 1998, 2679 DOI: 10.1039/A806604C
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