Synthesis and luminescence behaviour of rhenium(I) diynyl complexes. X-Ray crystal structures of [Re(CO)3(tBu2bpy)(C
C–C
CH)] and [Re(CO)3(tBu2bpy)(C
C–C
CPh)]
Abstract
Luminescent rhenium(I) diynyl complexes [Re(CO)3(tBu2- bpy)(CC–C
CH)] and [Re(CO)3(tBu2bpy)(C
C–C
CPh)] were synthesized and their photophysical properties studied; the crystal structures have also been determined.