Issue 13, 1998

Synthesis and structure of the heterobimetallic oxo complex [(thf)(Me2NH)2Cl2CrIII]2{ClSnII(µ-O)}2

Abstract

The reaction of [Sn(NMe2)2] with a suspension of CrCl3 and H2O in thf gives the molecular CrIIISnII oxo complex [(thf)(Me2NH)2Cl2Cr]2{ClSn(µ-O)}2 1, in which the O atoms of a central Sn2O2 ring coordinate two CrIII cations.

Article information

Article type
Paper

Chem. Commun., 1998, 1341-1342

Synthesis and structure of the heterobimetallic oxo complex [(thf)(Me2NH)2Cl2CrIII]2{ClSnII(µ-O)}2

M. A. Beswick, M. E. G. Mosquera, J. S. Palmer, D. S. Wright, M. A. Beswick, N. Choi and M. McPartlin, Chem. Commun., 1998, 1341 DOI: 10.1039/A802205D

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