Synthesis and structure of the heterobimetallic oxo complex [(thf)(Me2NH)2Cl2CrIII]2{ClSnII(µ-O)}2
Abstract
The reaction of [Sn(NMe2)2] with a suspension of CrCl3 and H2O in thf gives the molecular CrIIISnII oxo complex [(thf)(Me2NH)2Cl2Cr]2{ClSn(µ-O)}2 1, in which the O atoms of a central Sn2O2 ring coordinate two CrIII cations.