Issue 13, 1998

Mukaiyama aldol reactions of π-allyltricarbonyliron lactone and lactam complexes bearing trimethylsilyl enol ether side-chains. Not just formal, but genuine 1,7 induction of chirality

Abstract

A comparison of diastereoselectivities in the Mukaiyama aldol reactions of three types of trimethylsilyl enol ether substituted iron carbonyl complexes has provided evidence for the stereodirecting effect of remote substituents in π-allyltricarbonyliron lactone and lactam complexes.

Article information

Article type
Paper

Chem. Commun., 1998, 1339-1340

Mukaiyama aldol reactions of π-allyltricarbonyliron lactone and lactam complexes bearing trimethylsilyl enol ether side-chains. Not just formal, but genuine 1,7 induction of chirality

S. V. Ley, B. Middleton and J. M. Worrall, Chem. Commun., 1998, 1339 DOI: 10.1039/A802878H

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