Isonitriles are shown to form stable neutral adducts with some group 1 and 2 metal complexes; the synthesis and structures of [L![[upper bond 1 start]](https://www.rsc.org/images/entities/char_e010.gif)
i{N(R)C(Ph)N![[upper bond 1 end]](https://www.rsc.org/images/entities/char_e011.gif)
C(Ph)![[double bond, length half m-dash]](https://www.rsc.org/images/entities/char_e006.gif)
CR2}(CNPh)]2, [LiNR2(CNPh)]2, [Mg(CHR2)2(CNC6H3Me2-2,6)2] and [Mg(CHR2)(µ-Br)(CNBut)]2 are described (R = SiMe3).
C. F. Caro, P. B. Hitchcock, M. F. Lappert and M. Layh, Chem. Commun., 1998, 1297 DOI: 10.1039/A708976G
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