Issue 12, 1998
From the journal:

Chemical Communications

Synthesis, structure and Co–C bond homolysis of an intramolecularly bridged (tetrahydrofurfuryl)cobalt(salen) complex: a simple model of enzyme-bound coenzyme B12

Rolf Blaauw,   Juul L. van der Baan,   Sijbe Balt,   Martinus W. G. de Bolster,   Gerhard W. Klumpp,   Huub Kooijman  and  Anthony L. Spek  

Abstract

Air oxidation of a CoII(salen) derivative, whose ethanediyl moiety carries a methylene-linked 4-hydroxypent-1-en-3-yl substituent, yields an intramolecularly bridged (tetrahydrofurfuryl)CoIII(salen) complex of which the crystal structure has been determined; this B12 model is very resistant to Co–C bond homolysis, even in the presence of a large excess of the radical trap TEMPO.

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Article information

DOI
https://doi.org/10.1039/A801579A
Article type
Paper

Chem. Commun., 1998, 1295-1296

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Synthesis, structure and Co–C bond homolysis of an intramolecularly bridged (tetrahydrofurfuryl)cobalt(salen) complex: a simple model of enzyme-bound coenzyme B12

R. Blaauw, J. L. van der Baan, S. Balt, M. W. G. de Bolster, G. W. Klumpp, H. Kooijman and A. L. Spek, Chem. Commun., 1998, 1295 DOI: 10.1039/A801579A

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