Issue 5, 1998

A new type of allylation: synthesis of β,γ-unsaturated ketones from α-halogenated aryl ketones using an allyltributyltin(IV)–tin(II) dichloride–acetonitrile system

Abstract

Allylation of α-halogenated aryl ketones with an allyltributyltin–tin dichloride–acetonitrile system gave β,γ-unsaturated ketones in high yields via selective aryl rearrangement.

Article information

Article type
Paper

Chem. Commun., 1998, 563-564

A new type of allylation: synthesis of β,γ-unsaturated ketones from α-halogenated aryl ketones using an allyltributyltin(IV)–tin(II) dichloride–acetonitrile system

M. Yasuda, M. Tsuchida and A. Baba, Chem. Commun., 1998, 563 DOI: 10.1039/A708679B

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