Zirconocene enolate radical cations are generated and characterised in solution for the first time; the sterically congested radical cations undergo a mesolytic Zr–O bond cleavage process yielding zirconocene cations, the kinetics of which are determined.
M. Schmittel and R. Söllner, Chem. Commun., 1998, 565 DOI: 10.1039/A708495A
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