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Issue 14, 1998
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Synthesis and characterization of new titanium hexanuclear oxo carboxylato alkoxides. Molecular structure of [Ti63-O)6(µ-O2CC6H4OPh)6(OEt)6]

Abstract

The reaction between Ti(OR)4 (R = Et or Pri) and 2-phenoxybenzoic acid in refluxing toluene led to [Ti63-O)6(µ-O2CC6H4OPh)6(OR)6]; its structure corresponds to an assembly of two staggered triangular units sharing six edges (actually the µ3-O ligands) and connected via the carboxylate ligands.

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Supplementary files


Article type: Paper
DOI: 10.1039/A803266A
J. Chem. Soc., Dalton Trans., 1998, 2285-2288

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    Synthesis and characterization of new titanium hexanuclear oxo carboxylato alkoxides. Molecular structure of [Ti63-O)6(µ-O2CC6H4OPh)6(OEt)6]

    R. Papiernik, L. G. Hubert-Pfalzgraf, J. Vaissermann and M. C. Henriques Baptista Goncalves, J. Chem. Soc., Dalton Trans., 1998, 2285
    DOI: 10.1039/A803266A

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