The new redox-active cluster compounds [Ru6C(CO)14(η6-C6H4C8H16O5)] and [Ru6C(CO)14(η6-C6H4C10H20O6)] have been synthesised by direct reaction of the aryl crown ether with the hexaruthenium carbido cluster [Ru6C(CO)17] and display host–guest type behaviour with cations Na+ and NH4+ both spectroscopically and electrochemically.
D. S. Shephard, B. F. G. Johnson, J. Matters and S. Parsons, J. Chem. Soc., Dalton Trans., 1998, 2289 DOI: 10.1039/A803084G
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