Issue 2, 1997

1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring.

Abstract

Rapid and reversible migrations of the phenylsulfanyl group around the seven-membered ring of 7-phenylsulfanylcyclohepta-1,3,5-triene have been proved to proceed through successive 1,7-sigmatropic shifts with an energy barrier (ΔG298 in the range of 19.5-20.1kcal mol -1.

Article information

Article type
Paper

Mendeleev Commun., 1997,7, 50-51

1,7-Sigmatropic shifts of the phenylsulfanyl group along the perimeter of the cycloheptatriene ring.

G. A. Dushenko, I. E. Mikhailov, A. Zschunke, N. Hakam, C. Mugge and V. I. Minkin, Mendeleev Commun., 1997, 7, 50 DOI: 10.1070/MC1997v007n02ABEH000669

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