Trimethylsilyl derivatives as final nucleophiles in the tandem sequence of an ArSCl-initiated AdE reaction resulting in the synthesis of polyfunctional compounds

Abstract

The use of allyl silanes and silyl vinyl ethers in the final step of a Lewis acid-mediated sequence involving reaction of ArSCl, two vinyl ether units and a C-nucleophile has been studied, thereby allowing introduction of functional groups into the four-component adduct.