Co-ordinative activation of phosphaalkynes: methyl neopentylidene
phosphorane complexes of ruthenium(II); crystal structure of
[Ru(MeP![[double bond, length as m-dash]](https://www.rsc.org/images/entities/char_e001.gif)
CHBut
)Cl(I)(CO)(PPh3)
2]
Abstract
The reactions of
[Ru(PCHBut)Cl(CA)(PPh3)2]
(A = O or S) with iodomethane provided the phosphaalkene
complexes
[Ru(PMeCHBut)Cl(I)(CA)(PPh3)2]
(I trans to phosphaalkene), with one example
(A = O) having been crystallographically
characterised.
CHBut)Cl(CA)(PPh3)2]
(A = O or S) with iodomethane provided the phosphaalkene
complexes
[Ru(PMeCHBut)Cl(I)(CA)(PPh3)2]
(I trans to phosphaalkene), with one example
(A = O) having been crystallographically
characterised.
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![[double bond, length as m-dash]](https://www.rsc.org/images/entities/h2_char_e001.gif)
CHBut
)Cl(I)(CO)(PPh3)
2]