Issue 19, 1997
From the journal:

Chemical Communications

Synthesis of Fe4(CO)8(µ-PPh2)2(µ4-η1,η1,η2,η2-C2Ph)2via coupling of acetylides at a binuclear centre: a molecule with through-the-cluster carbon–carbon bonding?

Arthur J. Carty,   Graeme Hogarth,   Gary Enright,   Gilles Frapper,   Arthur J. Carty  and  Graeme Hogarth  

Abstract

Thermolysis of Fe2(CO)6(µ-PPh2)(µ-η1,η2-C2Ph) affordsthe rectangular cluster Fe4(CO)8(µ-PPh2)2(µ4-η1,η1,η2,η2-C2Ph)2 with two face-capping acetylides linked through the Fe4 face by a short carbon–carbon contact: reaction with CO leads to Fe3(CO)8{µ-Ph2PC(CPh)[double bond, length half m-dash]C(CPh)PPh2} as a result of C–C and C–P bond-forming processes.

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Article information

DOI
https://doi.org/10.1039/A704074A
Article type
Paper

Chem. Commun., 1997, 1883-1884

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Synthesis of Fe4(CO)8(µ-PPh2)2(µ4-η1,η1,η2,η2-C2Ph)2via coupling of acetylides at a binuclear centre: a molecule with through-the-cluster carbon–carbon bonding?

A. J. Carty, G. Hogarth, G. Enright, G. Frapper, A. J. Carty and G. Hogarth, Chem. Commun., 1997, 1883 DOI: 10.1039/A704074A

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