Issue 15, 1997

Efficient coupling reactions of allylamines with soft nucleophiles using nickel-based catalysts

Abstract

Substitution reactions of N,N-diethylallylamine 1 with soft nucleophiles such as active methylene compounds 2a–c and piperidine 5 proceed much more rapidly in the presence of Ni(dppb) 2 [dppb = 1,4-bis(diphenylphosphino)butane] as catalyst than with comparable palladium systems.

Article information

Article type
Paper

Chem. Commun., 1997, 1393-1394

Efficient coupling reactions of allylamines with soft nucleophiles using nickel-based catalysts

H. Bricout, J. Carpentier and A. Mortreux, Chem. Commun., 1997, 1393 DOI: 10.1039/A702954C

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