Issue 3, 1997
From the journal:

Chemical Communications

Synthesis, crystal structure and rearrangement of a methylene(ylene)- phosphorane containing a CH2-moiety at an sp2-hybridized phosphorus(v) centre

Bernd Schinkels,   Alexander Ruban,   Martin Nieger  and  Edgar Niecke  

Abstract

The reaction of the iminophosphane, (Me 3 Si) 3 C–P[double bond, length as m-dash]N–Mes*, with Me 2 S[double bond, length as m-dash]CH 2 affords the first methylenephosphorane containing a CH 2 moiety at an sp 2 -hybridized phosphorus(V) centre; the crystal structure as well the rearrangement of which is reported.

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Article information

DOI
https://doi.org/10.1039/A607402B
Article type
Paper

Chem. Commun., 1997, 293-294

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Synthesis, crystal structure and rearrangement of a methylene(ylene)- phosphorane containing a CH2-moiety at an sp2-hybridized phosphorus(v) centre

B. Schinkels, A. Ruban, M. Nieger and E. Niecke, Chem. Commun., 1997, 293 DOI: 10.1039/A607402B

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