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Issue 17, 1997
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Oxidative trimerization of o-dialkoxybenzenes to hexaalkoxytriphenylenes: molybdenum(v) chloride as a novel reagent

Abstract

Symmetrically substituted hexaalkoxytriphenylenes are obtained from o-dialkoxybenzenes by oxidative trimerization with MoCl 5 in high yields; oxidative coupling of a 3,3′,4,4′-tetraalkoxybiphenyl and 1,2-dialkoxybenzenes yields unsymmetrically substituted derivatives of triphenylene and a direct coupling of a 3,3′,4,4′-tetraalkoxybiphenyl with alkoxyphenol produces the monofunctionalized triphenylenes.

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Article information


Chem. Commun., 1997, 1615-1666
Article type
Paper

Oxidative trimerization of o-dialkoxybenzenes to hexaalkoxytriphenylenes: molybdenum(v) chloride as a novel reagent

S. Kumar and M. Manickam, Chem. Commun., 1997, 1615
DOI: 10.1039/A704130F

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