Issue 17, 1997
From the journal:

Chemical Communications

New route to functionalized cyclohexenes from nitromethane and electrophilic alkenes without solvent under focused microwave irradiation

David Michaud,   Sahar Abdallah-El Ayoubi,   Marie-Joëlle Dozias,   Loïc Toupet,   Françoise Texier-Boullet  and  Jack Hamelin  

Abstract

Nitromethane reacts via a diastereoselective double Michael addition with electrophilic alkenes activated by cyano and methoxycarbonyl groups [XC 6 H 4 CH[double bond, length as m-dash]C(CN)CO 2 Me] in the presence of catalytic amounts of piperidine under solvent-free conditions coupled with focused microwave irradiation to afford new, highly functionalized cyclohexenes; no cyclopropane formation is observed.

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Article information

DOI
https://doi.org/10.1039/A704241H
Article type
Paper

Chem. Commun., 1997, 1613-1614

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New route to functionalized cyclohexenes from nitromethane and electrophilic alkenes without solvent under focused microwave irradiation

D. Michaud, S. Abdallah-El Ayoubi, M. Dozias, L. Toupet, F. Texier-Boullet and J. Hamelin, Chem. Commun., 1997, 1613 DOI: 10.1039/A704241H

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