Novel spirobis(oxazolines) provide excellent levels of stereocontrol in copper-catalysed Diels–Alder reactions; the larger the ligand bite angle the higher the enantioselection (up to 98.4% ee).
I. W. Davies, L. Gerena, L. Castonguay, C. H. Senanayake, R. D. Larsen, T. R. Verhoeven and P. J. Reider, Chem. Commun., 1996, 1753 DOI: 10.1039/CC9960001753
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