The cerium(III)-mediated addition of diethyl (lithiodifluoromethyl)phosphonate to a benzoquinone monoketal allows the synthesis of phenol bearing the (diethoxyphosphonyl)difluoromethyl group via short, scaleable reaction sequences which avoid the use of the DAST reagent.
K. Blades, G. S. Cockerill, H. J. Easterfield, T. P. Lequeux and J. M. Percy, Chem. Commun., 1996, 1615 DOI: 10.1039/CC9960001615
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