Issue 14, 1996

On the atomic environment and the mode of action of the catalytic centre in an intercalated oxo–molybdenum complex [MoO2{O2CC(S)Ph2}2]2– for oxygen-transfer reactions

Abstract

The title anion accommodated as a pillar in the interlamellar space of a Zn(II)AlIII double hydroxide(hydrotalcite-like) host is shown by X-ray absorption spectroscopy, supplemented by other studies, to possess three terminal Mo[double bond, length half m-dash]O groups, in contrast to the two that exist in the dispersed, catalytically active anion.

Article information

Article type
Paper

Chem. Commun., 1996, 1613-1614

On the atomic environment and the mode of action of the catalytic centre in an intercalated oxo–molybdenum complex [MoO2{O2CC(S)Ph2}2]2– for oxygen-transfer reactions

A. Corma, F. Rey, J. M. Thomas, G. Sankar, G. N. Greaves, A. Cervilla, E. Llopis and A. Ribeira, Chem. Commun., 1996, 1613 DOI: 10.1039/CC9960001613

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