BunTeSiMe3 reacts with silver(I) chloride in the presence of PEt3 to yield the following series of cluster complexes depending on the relative amount of phosphine used: [Ag6(µ3-TeBun)4(µ-TeBun)2(PEt3)4] 1, [Ag32(µ3-TeBun)18-Te7(PEt3)6] 2 and [Ag48(µ3-TeBun)24Te12(PEt3)14] 3; the molecular structures of 2 and 3 are described.
J. F. Corrigan and D. Fenske, Chem. Commun., 1996, 943 DOI: 10.1039/CC9960000943
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