A series of sequential transformations on irradiation of the readily available cyclic azimines 2 lead to saturated pyrrolo[2,3-b]indoles 3, the mechanism of which is confirmed by isolation of photolabile intermediates 4 and 7 and two crystallographic determinations.
C. Byrne, J. P. James, C. Long and D. J. Wilcock, Chem. Commun., 1996, 945 DOI: 10.1039/CC9960000945
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