A ruthenium(II) complex generated in situ from [{RuCl2(η6-C6Me6)}2], (1S,2S)-2-methylamino-1,2-diphenylethanol and KOH serves as an efficient catalyst for asymmetric transfer hydrogenation of acetophenone derivatives in propan-2-ol to give (S)-enriched alcohols in up to 92% ee and in > 90% yield.
J. Takehara, S. Hashiguchi, A. Fujii, S. Inoue, T. Ikariya and R. Noyori, Chem. Commun., 1996, 233 DOI: 10.1039/CC9960000233
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