Issue 2, 1996
From the journal:

Chemical Communications

Synthesis and characterization of [NBu4][Pt3(µ-PPh2)2(C6F5)5]: an anionic cluster containing an unusual µ3-PPh2 bridging system

Ester Alonso,   Juan Forniés,   Consuelo Fortuño,   Antonio Martín  and  A. Guy Orpen  

Abstract

[NBu4]2[Pt2(µ-PPh2)2(C6F5)4] reacts with cis-[Pt(C6F5)2(thf)2](1:2 molar ratio) yielding [NBu4][Pt3(µ-PPh2)2(C6F5)5] which contains unusual µ3-PPh(1,2-η2-Ph)-κ3P phosphido and semi-bridging C6F5 ligands and two Pt–Pt bonds of length 2.899(1) and 2.772(1)Å.

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Article information

DOI
https://doi.org/10.1039/CC9960000231
Article type
Paper

Chem. Commun., 1996, 231-232

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Synthesis and characterization of [NBu4][Pt3(µ-PPh2)2(C6F5)5]: an anionic cluster containing an unusual µ3-PPh2 bridging system

E. Alonso, J. Forniés, C. Fortuño, A. Martín and A. G. Orpen, Chem. Commun., 1996, 231 DOI: 10.1039/CC9960000231

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