Reaction of octahydridooctasesquisiloxane with Co2(CO)8 in hexane affords the complex [Si8O12H6]{Co(CO)4}2 which on pyrolysis at 300 °C in vacuo gives nanoparticulate Co2C encapsulated in an amorphous siliceous matrix; the magnetic coercivity of this material is 3.5 kOe.
P. G. Harrison and R. Kannengiesser, J. Chem. Soc., Chem. Commun., 1995, 2065 DOI: 10.1039/C39950002065
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