Silver(I) glutarate is a 2D polynuclear polymer whose repeat unit consists of a tetranuclear silver cluster coordinated by two bridging glutarate anions; these units are organised, through additional metal–oxygen linkages, in layers parallel to the ac plane, in which uncommon metal–metal contacts (3.14–3.43 Å) are observed.
A. Michaelides, S. Skoulika, V. Kiritsis and A. Aubry, J. Chem. Soc., Chem. Commun., 1995, 1415 DOI: 10.1039/C39950001415
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