Issue 9, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Reversible cyclisation reactions to form ruthenafurans: X-ray crystal structure of [Ru(CO){C(Ph)OC(OEt)[double bond, length half m-dash]CH}Cl(PMe2Ph)2]

Martin P. Waugh,   Paul D. Morran,   Roger J. Mawby,   Fritjof C. F. Körber,   Amanda J. Reid  and  Colin D. Reynolds  

Abstract

Ruthenafurans [R[graphic omitted]H}ClL2](L = PMe2Ph, R = CH[double bond, length half m-dash]CHOEt, CH[double bond, length half m-dash]CHCMe3, Me or Ph; L = PMe3, R = CH[double bond, length half m-dash]CHOEt or CH[double bond, length half m-dash]CHPh) can be formed reversibly from [Ru(CO)2RClL2] and EtOC[triple bond, length half m-dash]CH: the rate-determining forward step involves the formation of the intermediate [Ru(CO)(COR)ClL2], which can be trapped when the reverse reaction occurs in the presence of Me3CNC.

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Article information

DOI
https://doi.org/10.1039/C39950000941
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 941-942

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Reversible cyclisation reactions to form ruthenafurans: X-ray crystal structure of [Ru(CO){C(Ph)OC(OEt)[double bond, length half m-dash]CH}Cl(PMe2Ph)2]

M. P. Waugh, P. D. Morran, R. J. Mawby, F. C. F. Körber, A. J. Reid and C. D. Reynolds, J. Chem. Soc., Chem. Commun., 1995, 941 DOI: 10.1039/C39950000941

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