Barium ruthenate, BaRuO3(OH)2, when dissolved in TFA–CH2Cl2 containing a few equivalents of 2,2′-bipyridine, generates a highly reactive ruthenium–oxo system that is capable of oxidizing ethane and propane at room temperature with good yields.
T. Lau and C. Mak, J. Chem. Soc., Chem. Commun., 1995, 943 DOI: 10.1039/C39950000943
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