The exposed nitrogen atom of the p-pyridylimido ligand in the vanadium(V) species [(N3N)V![[triple bond, length half m-dash]](https://www.rsc.org/images/entities/char_e007.gif)
N-C5H4N]1{N3N =[(Me3SiNCH2CH2)3N]3–} provides a reactive site capable of complexing a second metal fragment, enabling the construction of new types of heterobimetallic complexes linked by a compact conjugated bridge.
P. L. Hill, G. P. A. Yap, A. L. Rheingold and E. A. Maatta, J. Chem. Soc., Chem. Commun., 1995, 737 DOI: 10.1039/C39950000737
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