The synthesis of two new large cryptands 7a and 7b has been carried out and the X-ray structure of 7b confirms that a benzene guest molecule is encapsulated centrally in its cavity.
R. J. A. Janssen, L. F. Lindoy, O. A. Matthews, G. V. Meehan, A. N. Sobolev and A. H. White, J. Chem. Soc., Chem. Commun., 1995, 735 DOI: 10.1039/C39950000735
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