The reaction of dichloro(cycloocta-1,5-diene)palladium(II) with l-dipheny (L1) or 1-phenyl(n-butyl)-phosphino-1′-[6-(2,2′-bipyridyl)]ferrocene (L2) results in the novel trans-coordination geometry with the β-pyridinyl ring and the phosphine group binding to the metal centre, as proved by a crystal structure determination of [PdCl2L1][PdCl2(cod)].
I. R. Butler, M. Kalaji, L. Nehrlich, M. Hursthouse, A. I. Karaulov and K. M. A. Malik, J. Chem. Soc., Chem. Commun., 1995, 459 DOI: 10.1039/C39950000459
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