Issue 2, 1995
From the journal:

Journal of the Chemical Society, Chemical Communications

Cleavage of both alkyl C–H bonds and aryl C–F bonds and concomitant C–C bond formation in a pentamethylcyclopentadienylrhodium phosphine complex: X-ray structure of [η5-C5Me3[CH2C6F4P(C6F5)CH2]2-1,3}RhCl]+BF4–

Malcolm J. Atherton,   John Fawcett,   John H. Holloway,   Eric G. Hope,   Atilla Karaçar,   David R. Russell  and  Graham C. Saunders  

Abstract

The reaction between bis(dipentafluorophenylphosphino)ethane, dfppe, and [{(η5-C5Me5)RhCl(µ-Cl)}2] proceeds with cleavage of two C–F bonds and two C–H bonds and formation of two C–C bonds to yield the ionic complex 1a.

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Article information

DOI
https://doi.org/10.1039/C39950000191
Article type
Paper

J. Chem. Soc., Chem. Commun., 1995, 191-192

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Cleavage of both alkyl C–H bonds and aryl C–F bonds and concomitant C–C bond formation in a pentamethylcyclopentadienylrhodium phosphine complex: X-ray structure of [η5-C5Me3[CH2C6F4P(C6F5)CH2]2-1,3}RhCl]+BF4–

M. J. Atherton, J. Fawcett, J. H. Holloway, E. G. Hope, A. Karaçar, D. R. Russell and G. C. Saunders, J. Chem. Soc., Chem. Commun., 1995, 191 DOI: 10.1039/C39950000191

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