The novel bis(benzene) complex [Os3(CO)6(µ3: η2:η2: η2-C6H6)(η6-C6H6)] is prepared and characterised by single-crystal X-ray analysis; the cluster exhibits two distinct coordination modes of benzene, one terminally bound in an η6 manner, the other in a µ3 face-capping coordination mode.
S. L. Ingham, B. F. G. Johnson and J. G. M. Nairn, J. Chem. Soc., Chem. Commun., 1995, 189 DOI: 10.1039/C39950000189
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